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Poly[[μ-1,4-bis-(pyridin-4-ylmeth-yl)piperazine]bis-[μ3-4-(2-carboxyl-atoeth-yl)benzoato]dicopper(II)].

ABSTRACT: In the title coordination polymer, [Cu2(C9H6O4)2(C16H20N4)]n, the CuII atoms in {NO4} square-pyramidal coordination environments are conjoined into diperiodic coordination polymer slabs by the full span of the bridging 1,4-bis-(pyridin-4-ylmeth-yl)piperazine (bpmp) and 4-(carboxyl-eth-yl)benzoate (ceb) ligands. The slab motifs are expanded into the full crystal structure by means of longer-range C-H⋯O attractive inter-actions.

SUBMITTER: Jia J 

PROVIDER: S-EPMC10483545 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature

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Poly[[μ-1,4-bis-(pyridin-4-ylmeth-yl)piperazine]bis-[μ<sub>3</sub>-4-(2-carboxyl-atoeth-yl)benzoato]dicopper(II)].

Jia Jason J   LaDuca Robert L RL  

IUCrData 20230830 Pt 8

In the title coordination polymer, [Cu<sub>2</sub>(C<sub>9</sub>H<sub>6</sub>O<sub>4</sub>)<sub>2</sub>(C<sub>16</sub>H<sub>20</sub>N<sub>4</sub>)]<sub><i>n</i></sub>, the Cu<sup>II</sup> atoms in {NO<sub>4</sub>} square-pyramidal coordination environments are conjoined into diperiodic coordination polymer slabs by the full span of the bridging 1,4-bis-(pyridin-4-ylmeth-yl)piperazine (bpmp) and 4-(carboxyl-eth-yl)benzoate (ceb) ligands. The slab motifs are expanded into the full crystal structur  ...[more]

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