Crystal structures of the complexes containing macrocyclic cations [M(cyclam)]²⁺ (M = Ni, Zn) and tetra-iodido-cadmate(2-) anion.

ABSTRACT: The asymmetric units of the isostructural compounds (1,4,8,11-tetra-aza-cyclo-tetra-decane-κ⁴ N)nickel(II) tetra-iodido-cadmate(II), [Ni(C₁₀H₂₄N₄)][CdI₄] (I), and tri-iodido-1κ³ I-μ-iodido-(1,4,8,11-tetra-aza-cyclo-tetra-decane-2κ⁴ N)cad-mium(II)zinc(II), [CdZnI₄(C₁₀H₂₄N₄)] (II) (C₁₀H₂₄N₄ = 1,4,8,11-tetra-aza-cyclo-tetra-decane, cyclam, L), consist of the centrosymmetric macrocyclic cation [M(L)]²⁺ [M = Ni^II or Zn^II] with the metal ion lying on a twofold screw axis, and the tetra-iodo-cadmate anion [CdI₄]^2- located on the

SUBMITTER: Andriichuk IL 

PROVIDER: S-EPMC10483555 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature