Synthesis, structure and Hirshfeld surface analysis of a coordination compound of cadmium acetate with 2-amino-benzoxazole.

ABSTRACT: A first coordination compound of 2-amino-benzoxazole (2AB), namely, bis-(2-amino-benzoxazole-κN ³)bis-(acetato-κ² O,O')cadmium(II), [Cd(CH₃COO)₂(2AB)₂], has been synthesized from ethanol solutions of Cd(CH₃(COO)₂ and 2AB. In the monoclinic crystals with the space group C2₁/c, the cadmium ions coordinate two neutral 2AB mol-ecules in a monodentate fashion through the oxazole N atom, while two acetate ligands are coordinated through the O atoms in a bidentate manner. The coordination polyhedron of the central ion is substanti-ally distorted octa-hedral. There are two relatively strong intra-molecular hydrogen bonds in the complex mol-ecule. Ad

SUBMITTER: Razzoqova S 

PROVIDER: S-EPMC10483566 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature