Photo-Induced Active Lewis Acid-Base Pairs in a Metal-Organic Framework for H₂ Activation.

ABSTRACT: The establishment of active sites as the frustrated Lewis pair (FLP) has recently attracted much attention ranging from homogeneous to heterogeneous systems in the field of catalysis. Their unquenched reactivity of Lewis acid and base pairs in close proximity that are unable to form stable adducts has been shown to activate small molecules such as dihydrogen heterolytically. Herein, we show that grafted Ru metal-organic framework-based catalysts prepared via N-containing linkers are rather catalytically inactive for H₂ activation despite the application of elevated temperatures. However, upon light illumination, charge polarization of the anchored Ru bipyridine complex can form a transient Lewis acid-base pair, Ru⁺-N^- via metal-to-ligand charge transfer, as

SUBMITTER: Ng BKY 

PROVIDER: S-EPMC10485891 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature