High-Efficiency Photoinduced Charge Separation in Fe(III)carbene Thin Films.

ABSTRACT: Symmetry-breaking charge separation in molecular materials has attracted increasing attention for optoelectronics based on single-material active layers. To this end, Fe(III) complexes with particularly electron-donating N-heterocyclic carbene ligands offer interesting properties with a ²LMCT excited state capable of oxidizing or reducing the complex in its ground state. In this Communication, we show that the corresponding symmetry-breaking charge separation occurs in amorphous films of pristine [Fe(III)L₂]PF₆ (L = [phenyl(tris(3-methylimidazol-2-ylidene))borate]^-). Excitation of the solid material with visible light leads to ultrafast electron transfer quenching of the ²LMCT excited state, generating Fe(II) and Fe(IV) products

SUBMITTER: Zhang M 

PROVIDER: S-EPMC10485928 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature