Single-Molecule Magnet Properties in 3d4f Heterobimetallic Iron and Dysprosium Complexes Involving Hydrazone Ligand.
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ABSTRACT: The reaction between the ((E)-N'-(2-hydroxy-3-methoxybenzylidene)pyrazine-2-carbohydrazide) (H2opch) ligand and the metallo-precursor [Dy(hfac)3]·2H2O led to the formation of an homometallic coordination complex with the formula [Dy2(hfac)3(H2O)(Hopch)2][Dy(hfac)4] (1). In presence of both [Dy(hfac)3] 2H2O and the Fe(II) salt, the heterobimetallic tetranuclear [FeDy3(hfac)8(H2O)2(opch)2] (2) was isolated, while the addition of the co-ligand 1,2-Bis(2-hydroxy-3-methoxybenzylidene) hydrazine (H2bmh) led to the formation of two heterobimetallic tetranuclear complexes with the formula [Fe
SUBMITTER: Lefeuvre B
PROVIDER: S-EPMC10489976 | biostudies-literature | 2023 Aug
REPOSITORIES: biostudies-literature
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