Gas-phase formation of the resonantly stabilized 1-indenyl (C₉H₇^•) radical in the interstellar medium.

ABSTRACT: The 1-indenyl (C₉H₇^•) radical, a prototype aromatic and resonantly stabilized free radical carrying a six- and a five-membered ring, has emerged as a fundamental molecular building block of nonplanar polycyclic aromatic hydrocarbons (PAHs) and carbonaceous nanostructures in deep space and combustion systems. However, the underlying formation mechanisms have remained elusive. Here, we reveal an unconventional low-temperature gas-phase formation of 1-indenyl via barrierless ring annulation involving reactions of atomic carbon [C(³P)] with styrene (C₆H₅C₂H₃) and propargyl (C₃H₃^•) with phenyl (C₆H₅^•). Macroscopic environments like molecular c

SUBMITTER: Yang Z 

PROVIDER: S-EPMC10491290 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature