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Access to Unsaturated Organogermanes via (De)Hydrosilylation Mediated by Cobalt Complexes.

ABSTRACT: The functionalization of alkynylgermanes using hydrosilanes was accomplished by employing cobalt catalysis. Depending on the reactants used, the reaction can proceed via dehydrogenative coupling or hydrosilylation. Importantly, the presented method is characterized by mild reaction conditions, allowing rapid access to a wide range of organogermanes.

SUBMITTER: Broniarz K

PROVIDER: S-EPMC10496132 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature

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Access to Unsaturated Organogermanes via (De)Hydrosilylation Mediated by Cobalt Complexes.

Broniarz Konstancja K Hreczycho Grzegorz G

Organic letters 20230830 35

The functionalization of alkynylgermanes using hydrosilanes was accomplished by employing cobalt catalysis. Depending on the reactants used, the reaction can proceed via dehydrogenative coupling or hydrosilylation. Importantly, the presented method is characterized by mild reaction conditions, allowing rapid access to a wide range of organogermanes. ...[more]

PMID: 37646486

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