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Two-dimensional self-assembly and co-assembly of two tetracarboxylic acid derivatives investigated by STM.


ABSTRACT: In this work, the two-dimensional self-assembly and co-assembly behaviors of two tetracarboxylic acid derivatives (H4BDETP and H4BTB) were investigated by scanning tunneling microscopy (STM). H4BDETP molecules self-assembled into linear nanostructures, and H4BTB molecules formed lamellar and tetragonal nanostructures. The formation of a H4BDETP/H4BTB co-assembly nanostructure was closely related to the deposition sequence of H4BDETP and H4BTB on highly oriented pyrolytic graphite (HOPG). The introduction of H4BTB into the self-assembly system of H4BDETP resulted in the emergence of the H4BDETP/H4BTB nanostructure, while the addition of H4BDETP had no effect on the self-assembly system of H4BTB and a H4BDETP/H4BTB co-assembly nanostructure was not obtained.

SUBMITTER: Peng X 

PROVIDER: S-EPMC10496876 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature

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Two-dimensional self-assembly and co-assembly of two tetracarboxylic acid derivatives investigated by STM.

Peng Xuan X   Gan Linlin L   Zhai Wenchao W   Chen Xiaoling X   Deng Ke K   Duan Wubiao W   Li Wei W   Zeng Qingdao Q  

Nanoscale advances 20230803 18


In this work, the two-dimensional self-assembly and co-assembly behaviors of two tetracarboxylic acid derivatives (H<sub>4</sub>BDETP and H<sub>4</sub>BTB) were investigated by scanning tunneling microscopy (STM). H<sub>4</sub>BDETP molecules self-assembled into linear nanostructures, and H<sub>4</sub>BTB molecules formed lamellar and tetragonal nanostructures. The formation of a H<sub>4</sub>BDETP/H<sub>4</sub>BTB co-assembly nanostructure was closely related to the deposition sequence of H<sub  ...[more]

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