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Bimetallic Zeolitic Imidazole Frameworks for Improved Stability and Performance of Intrusion-Extrusion Energy Applications.

ABSTRACT: Hydrophobic flexible zeolitic imidazole frameworks (ZIFs) represent reference microporous materials in the area of mechanical energy storage, conversion, and dissipation via non-wetting liquid intrusion-extrusion cycle. However, some of them exhibit drawbacks such as lack of stability, high intrusion pressure, or low intrusion volume that make them non-ideal materials to consider as candidates for real applications. In this work, we face these limitations by exploiting the hybrid ZIF concept. Concretely, a bimetallic SOD-like ZIF consisting of Co and Zn ions was synthesized and compared with Co-ZIF (ZIF-67) and Zn-ZIF (ZIF-8) showing for the first time that the hybrid ZIF combines the good stability of ZIF-8 with the higher water intrusion volume of ZIF-67. Moreover, it is shown that the hybrid-ZIF approach can be used to tune the intrusion/extrusion pressure, which is crucial for technological applications.

SUBMITTER: Amayuelas E

PROVIDER: S-EPMC10518860 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature

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Bimetallic Zeolitic Imidazole Frameworks for Improved Stability and Performance of Intrusion-Extrusion Energy Applications.

Amayuelas Eder E Sharma Sandeep Kumar SK Utpalla Pranav P Mor Jaideep J Bartolomé Luis L Carter Marcus M Trump Benjamin B Yakovenko Andrey Andreevich AA Zajdel Pawel P Grosu Yaroslav Y

The journal of physical chemistry. C, Nanomaterials and interfaces 20230912 37

Hydrophobic flexible zeolitic imidazole frameworks (ZIFs) represent reference microporous materials in the area of mechanical energy storage, conversion, and dissipation via non-wetting liquid intrusion-extrusion cycle. However, some of them exhibit drawbacks such as lack of stability, high intrusion pressure, or low intrusion volume that make them non-ideal materials to consider as candidates for real applications. In this work, we face these limitations by exploiting the hybrid ZIF concept. Co ...[more]

PMID: 37752902

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Project description:A copper incorporated zeolitic imidazolate framework-8 (ZIF-8) has been synthesized and demonstrated to be a potential material for a peroxidase mimic. The resultant bimetallic Cu-Zn incorporated MOF is used for the dual mode sensing of hydrogen peroxide by following electrochemical as well as spectrophotometric methods. Using 3,3',5,5'-tetramethylbenzidine (TMB) as a chromogenic substrate, spectrophotometric studies are carried out, and the steady state kinetic parameters are determined for two different concentrations of Cu incorporated ZIF-8 (viz Cu@ZIF-8-1 and Cu@ZIF-8-2). It is found that both Cu@ZIF-8-1 and Cu@ZIF-8-2 exhibit more affinity toward the TMB substrate than the horseradish peroxidase (HRP) enzyme as indicated by the low Km values obtained for the substrate. Also, as the concentration of incorporated Cu increases, Vmax values are also found to be enhanced. Electrochemically, the Cu@ZIF-8 modified glassy carbon electrode (GCE) showed a good response for peroxide detection in the concentration range from 0.5 mM to 5 mM at a working potential of -0.25 V in PBS (pH 7.0) with a limit of detection (LOD) value of 0.46 mM and a sensitivity of 20.25 μA/mM. Further, the chromogenic substrate TMB is successfully immobilized on the electrode surface and subsequently used for the peroxide detection along with Cu@ZIF-8. Here, TMB acts as a mediator and shifted the working potential to 0.1 V in acetate buffer (pH 5.0) in the concentration range from 0.5 mM to 5 mM with an LOD value of 0.499 mM and a sensitivity of 0.097 μA/mM. Interestingly, the same electrode in PBS of pH 7.0 showed a response to peroxide at a working potential of -0.1 V in the concentration range from 0.5 mM to 5 mM with an LOD value of 0.143 mM and a sensitivity of 0.33 μA/mM. Moreover, the applicability of this material for peroxide sensing is evaluated using milk samples, and the proposed material is able to recover the peroxide present in milk. Thus, the bimetallic Cu-Zn MOF can be utilized for the dual mode sensing of peroxide and can be extended for various real time applications.

Dataset Information

Bimetallic Zeolitic Imidazole Frameworks for Improved Stability and Performance of Intrusion-Extrusion Energy Applications.

Publications

Bimetallic Zeolitic Imidazole Frameworks for Improved Stability and Performance of Intrusion-Extrusion Energy Applications.

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