Synthetic styrene-based bioinspired model of the [FeFe]-hydrogenase active site for electrocatalytic hydrogen evolution.

ABSTRACT: Integration of molecular catalysts inside polymeric scaffolds has gained substantial attention over the past decade, as it provides a path towards generating systems with enhanced stability as well as enzyme-like morphologies and properties. In the context of solar fuels research and chemical energy conversion, this approach has been found to improve both rates and energy efficiencies of a range of catalytic reactions. However, system performance still needs to be improved to reach technologically relevant currents and stability, parameters that are heavily influenced by the nature of the incorporated molecular catalyst. Here, we have focused on the integration of a biomimetic {Fe₂(μ-adt)(CO)₆} (-CH₂NHCH₂S-, azadithiolate or adt^2-) bas

SUBMITTER: Zamader A 

PROVIDER: S-EPMC10521030 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature