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Electronic Structures of Nickel(II)-Bis(indanyloxazoline)-dihalide Catalysts: Understanding Ligand Field Contributions That Promote C(sp²)-C(sp³) Cross-Coupling.

ABSTRACT: Ni^II(IB) dihalide [IB = (3aR,3a'R,8aS,8a'S)-2,2'-(cyclopropane-1,1-diyl)bis(3a,8a-dihydro-8H-indeno[1,2-d]-oxazole)] complexes are representative of a growing class of first-row transition-metal catalysts for the enantioselective reductive cross-coupling of C(sp²) and C(sp³) electrophiles. Recent mechanistic studies highlight the complexity of these ground-state cross-couplings but also illuminate new reactivity pathways stemming from one-electron redox and their significant sensitivities to reaction conditions. For the first time, a diverse array of spectroscopic methods coupled to electrochemistry have been applied to Ni^II-based precatalysts to evaluate specific ligand field

SUBMITTER: McNicholas BJ

PROVIDER: S-EPMC10530056 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature

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Dataset Information

Electronic Structures of Nickel(II)-Bis(indanyloxazoline)-dihalide Catalysts: Understanding Ligand Field Contributions That Promote C(sp²)-C(sp³) Cross-Coupling.

OmicsDI is part of the ELIXIR infrastructure

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Dataset Information

Electronic Structures of Nickel(II)-Bis(indanyloxazoline)-dihalide Catalysts: Understanding Ligand Field Contributions That Promote C(sp2)-C(sp3) Cross-Coupling.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Electronic Structures of Nickel(II)-Bis(indanyloxazoline)-dihalide Catalysts: Understanding Ligand Field Contributions That Promote C(sp²)-C(sp³) Cross-Coupling.