Revealing the closed pore formation of waste wood-derived hard carbon for advanced sodium-ion battery.

ABSTRACT: Although the closed pore structure plays a key role in contributing low-voltage plateau capacity of hard carbon anode for sodium-ion batteries, the formation mechanism of closed pores is still under debate. Here, we employ waste wood-derived hard carbon as a template to systematically establish the formation mechanisms of closed pores and their effect on sodium storage performance. We find that the high crystallinity cellulose in nature wood decomposes to long-range carbon layers as the wall of closed pore, and the amorphous component can hinder the graphitization of carbon layer and induce the crispation of long-range carbon layers. The optimized sample demonstrates a high reversible capacity of 430 mAh g^-1 at 20 mA g^-1 (plateau capacity of 293 mAh g^-1 for

SUBMITTER: Tang Z 

PROVIDER: S-EPMC10533848 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature