Evaluation of Mono and Bimetallic Ferrocene-Based 1,2,3-Triazolyl Compounds as Burning Rate Catalysts for Solid Rocket Motor.

ABSTRACT: We reported mono and bimetallic ferrocene-based 1,2,3-triazolyl compounds as potential burning rate catalysts in their neutral and ionic forms. All complexes reported here were characterized using ¹H and ¹³C NMR, elemental analysis, and Mössbauer spectroscopy, which was performed for neutral and oxide compounds. The complexes present quasireversible redox potentials with higher oxidative ability than ferrocene and catocene under the same conditions. The complexes were tested as catalysts on the thermal decomposition of ammonium perchlorate (AP) and examined by a differential scanning calorimetry technique to gain further knowledge about their catalytic behavior. Compound 1 causes a decrease of the high-temperature decomposition (HTD) of AP positively, decreasin

SUBMITTER: Valdebenito C 

PROVIDER: S-EPMC10536897 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature