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Photoredox Coupling of CO₂ Reduction with Benzyl Alcohol Oxidation over Ternary Metal Chalcogenides (Zn_mIn₂S_3+m, m = 1-5) with Regulable Products Selectivity.

ABSTRACT: Integrating photocatalytic CO₂ reduction with selective benzyl alcohol (BA) oxidation in one photoredox reaction system is a promising way for the simultaneous utilization of photogenerated electrons and holes. Herein, Zn_mIn₂S_3+m (m = 1-5) semiconductors (ZnIn₂S₄, Zn₂In₂S₅, Zn₃In₂S₆, Zn₄In₂S₇, and Zn₅In₂S₈) with various composition faults were synthesized via a simple hydrothermal method and used for effective selective dehydrocoupling of benzyl alcohol into high-value C-C coupling products and reduction of CO₂ into syngas under visible light. The absorption edge of Zn_mIn

SUBMITTER: Du Z

PROVIDER: S-EPMC10537807 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature

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Photoredox Coupling of CO₂ Reduction with Benzyl Alcohol Oxidation over Ternary Metal Chalcogenides (Zn_mIn₂S_3+m, m = 1-5) with Regulable Products Selectivity.

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Dataset Information

Photoredox Coupling of CO2 Reduction with Benzyl Alcohol Oxidation over Ternary Metal Chalcogenides (ZnmIn2S3+m, m = 1-5) with Regulable Products Selectivity.

OmicsDI is part of the ELIXIR infrastructure

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Photoredox Coupling of CO₂ Reduction with Benzyl Alcohol Oxidation over Ternary Metal Chalcogenides (Zn_mIn₂S_3+m, m = 1-5) with Regulable Products Selectivity.