Chromophore Planarity, -BH Bridge Effect, and Two-Photon Activity: Bi- and Ter-Phenyl Derivatives as a Case Study.

ABSTRACT: In this work, we have employed electronic structure theories to explore the effect of the planarity of the chromophore on the two-photon absorption properties of bi- and ter-phenyl systems. To that end, we have considered 11 bi- and 7 ter-phenyl-based chromophores presenting a donor-π-acceptor architecture. In some cases, the planarity has been enforced by bridging the rings at ortho-positions by -CH₂ and/or -BH, -O, -S, and -NH moieties. The results presented herein demonstrate that in bi- and ter-phenyl systems, the planarity achieved via a -CH₂ bridge increases the 2PA activity. However, the introduction of a bridge with the -BH moiety perturbs the electronic structure to a large extent, thus diminishing the two-photon transition strength to the lowest elect

SUBMITTER: Rajput SS 

PROVIDER: S-EPMC10544031 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature