Ruthenium(v) terminal arylimido corroles: isolation, spectroscopic characterization and reactivity.

ABSTRACT: Terminal Ru(v)-imido species are thought to be as reactive to group transfer reactions as their Ru(v)-oxo homologues, but are less studied. With the electron-rich corrole ligand, relatively stable and isolable Ru(v)-arylimido complexes [Ru(^tBu-Cor)(NAr)] (H₃(^tBu-Cor) = 5,15-diphenyl-10-(p-tert-butylphenyl)corrole, Ar = 2,4,6-Me₃C₆H₂ (Mes), 2,6-(ⁱPr)₂C₆H₃ (Dipp), 2,4,6-(ⁱPr)₃C₆H₂ (Tipp), and 3,5-(CF₃)₂C₆H₃ (BTF)) can be prepared from [Ru(^tBu-Cor)]₂ under strongly reducing conditions. This type of Ru(v)-monoarylimido corrole complex w

SUBMITTER: Shing KP 

PROVIDER: S-EPMC10548528 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature