Ontology highlight
ABSTRACT:
SUBMITTER: Rodriguez MR
PROVIDER: S-EPMC10552652 | biostudies-literature | 2023 Jan
REPOSITORIES: biostudies-literature
Rodríguez Manuel R MR M Rodríguez Anabel A López-Resano Sara S Pericàs Miquel A MA Díaz-Requejo M Mar MM Maseras Feliu F Pérez Pedro J PJ
ACS catalysis 20221223 1
In the context of copper-catalyzed nitrene transfer to olefins, many systems operate upon mixing a CuX salt (X = halide, OTf) and a polydentate N-based ligand, assuming that the X ligand is displaced from the coordination sphere toward a counterion position. Herein, we demonstrated that such general assumption should be in doubt since studies carried out with the well-defined copper(I) complexes (TTM)CuCl and [(TTM)Cu(NCMe)]PF<sub>6</sub> (TTM = tris(triazolyl)methane ligand) demonstrate a dual ...[more]