Potassium permanganate modification of hydrochar enhances sorption of Pb(II), Cu(II), and Cd(II).
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ABSTRACT: Hydrochars formed by hydrothermal carbonization of hickory wood, bamboo, and wheat straw at 200 °C were modified by potassium permanganate (KMnO4) for the sorption of Pb(II), Cd(II), and Cu(II). The wheat straw hydrochar (WSHyC) modified with 0.2 M KMnO4 resulted in the most promising adsorbent (WSHyC-0.2KMnO4). Characterization of WSHyC and WSHyC-0.2KMnO4 revealed that the modified hydrochar features large specific surface area, rich of surface oxygenic functional groups (OCFG), and a significant amount of MnOx micro-particles. Batch adsorption experiments indicated that the adsorption rate by WSHyC-0.2KMnO4 was faster than for WSHyC, attaining equilibrium after around 5 h. The optimum adsorption capacity (Langmuir) of Pb(II), Cd(II),
SUBMITTER: Zhang Y
PROVIDER: S-EPMC10558135 | biostudies-literature | 2023 Oct
REPOSITORIES: biostudies-literature
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