Synthesis, crystal structure and Hirshfeld surface analysis of (2Z,2'E)-2,2'-(3-meth-oxy-3-phenylpropane-1,2-diyl-idene)bis-(hydrazine-1-carbo-thioamide) di-methyl-formamide monosolvate.

ABSTRACT: The overall mol-ecular configuration of the title compound, C₁₂H₁₆N₆OS₂·C₃H₇NO, is stabilized in the solid state by intra-molecular C-H⋯N, C-H⋯O, N-H⋯N and N-H⋯O inter-actions, forming S(5) ring motifs. In the crystal, mol-ecules are linked to each other and solvent di-methyl-formamide mol-ecules by N-H⋯S, N-H⋯O, C-H⋯O and C-H⋯S hydrogen bonds, forming a three dimensional network. The phenyl ring of the title compound is disordered over two sites with an occupancy ratio of 0.57 (4):0.43 (4). A Hirshfeld surface analysis was performed to qu-antify the contributions of the different inter-molecular inter-actions, indicating that the most important contributions to the crystal packing are from H⋯H (38.7%), S⋯H / H⋯S (24.0%), C⋯H / H⋯C (18.5%) and N⋯H / H⋯N (9.8%) inter-actions.

SUBMITTER: Guseinov FI 

PROVIDER: S-EPMC10561204 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature