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Growth and characterization of a new inorganic metal-halide crystal structure, InPb2Cl5.


ABSTRACT: A new solid-state inorganic compound, indium dilead penta-chloride, InPb2Cl5, was synthesized by melting InCl and PbCl2 in a vacuum-sealed quartz ampoule. The ampoule was heated to 793 K and then slowly cooled to room temperature to induce crystallization of InPb2Cl5. InPb2Cl5 crystallizes in the monoclinic crystal system adopting a space group of type P21/c, which is isostructural with other metal halides such as RbPb2Cl5, KPb2Cl5 and TlPb2Cl5. The bulk InPb2Cl5 exhibits a metallic black/grey colour, allowing it to be separated from white/yellow PbCl2 crystals. Due to the incongruent nature of the compound, the pure bulk InPb2Cl5 was not obtained. The black/grey InPb2Cl5 crystals were characterized by powder and single-crystal X-ray diffraction. InPbCl3 was also explored, however the growth was unsuccessful.

SUBMITTER: Lewis MP 

PROVIDER: S-EPMC10561213 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature

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Growth and characterization of a new inorganic metal-halide crystal structure, InPb<sub>2</sub>Cl<sub>5</sub>.

Lewis Michael P MP   Kandel Ramjee R   Schatte Gabriele G   Wang Peng L PL  

Acta crystallographica. Section E, Crystallographic communications 20230926 Pt 10


A new solid-state inorganic compound, indium dilead penta-chloride, InPb<sub>2</sub>Cl<sub>5</sub>, was synthesized by melting InCl and PbCl<sub>2</sub> in a vacuum-sealed quartz ampoule. The ampoule was heated to 793 K and then slowly cooled to room temperature to induce crystallization of InPb<sub>2</sub>Cl<sub>5</sub>. InPb<sub>2</sub>Cl<sub>5</sub> crystallizes in the monoclinic crystal system adopting a space group of type <i>P</i>2<sub>1</sub>/<i>c</i>, which is isostructural with other me  ...[more]

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