Synthesis, crystal structure, stereochemical and Hirshfeld surface analysis of trans-di-aqua-bis-(1-phenyl-propane-1,2-di-amine-κ²N,N')nickel(II) dichloride dihydrate.

ABSTRACT: In the hydrated complex salt, [Ni(C₉H₁₄N₂)₂(H₂O)₂]Cl₂·2H₂O, the asymmetric unit comprises of half of the complex cation along with one chloride anion and one non-coordinating water mol-ecule. The central nickel(II) atom is located on an inversion center and is coordinated in a trans octa-hedral fashion by four N atoms from two bidentate 1,2-di-amino-1-phenyl-propane ligands in the equatorial plane, and by two oxygen atoms from two water mol-ecules occupying the axial sites. The five-membered chelate ring is in a slightly twisted envelope conformation. The crystal packing features O-H⋯Cl, N-H⋯O and N-H⋯Cl hydrogen bonds. Hirshfeld surface analysis revealed that the most important contributions to

SUBMITTER: Akila S 

PROVIDER: S-EPMC10561215 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature