catena-Poly[[di-aqua-bis-(1,3-di-hydro-3-oxo-isobenzo-furan-1-acetato)-copper(II)]-μ-N,N'-(ethane-1,2-di-yl)dinicotinamide].

ABSTRACT: The title compound, {[Cu(C₁₀H₇O₄)₂(C₁₄H₁₄N₄O₂)(H₂O)₂]_n, contains octa-hed-rally coordinated Cu^II ions ligated by two bis-(1,3-di-hydro-3-oxo-1-isobenzo-furan-acetate (dibf) ligands and two trans water mol-ecules, linked by N,N'-(ethane-1,2-di-yl)dinicotinamide (edn) ligands into mono-periodic coordination polymer chains. The dibf ligands exhibit a pseudo-mirror positional disorder over two positions in a 89.2 (3)/10.8 (3) ratio; the central amide groups of the edn ligands are disordered pseudo-rotationally in the same ratio. These mono-periodic chain motifs are held into supra-molecular di-periodic supra-molecular layers by means of

SUBMITTER: Pumford SR 

PROVIDER: S-EPMC10561234 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature