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Influence of core size on self-assembled molecular networks composed of C_3h-symmetric building blocks through hydrogen bonding interactions: structural features and chirality.

ABSTRACT: The effect of the core size on the structure and chirality of self-assembled molecular networks was investigated using two aromatic carboxylic acid derivatives with frameworks displaying C_3h symmetry, triphenylene derivative H3TTCA and dehydrobenzo[12]annulene (DBA) derivative DBACOOH, each having three carboxy groups per molecule. Scanning tunneling microscopy observations at the 1-heptanoic acid/graphite interface revealed H3TTCA exclusively forming a chiral honeycomb structure, and DBACOOH forming three structures (type I, II, and III structures) depending on its concentration and whether the system is subjected to annealing treatment. Hydrogen bonding interaction patterns and chirality were carefully analyzed based on a modeling study using molecular mechanics simulat

SUBMITTER: Maeda M

PROVIDER: S-EPMC10562897 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature

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Influence of core size on self-assembled molecular networks composed of C_3h-symmetric building blocks through hydrogen bonding interactions: structural features and chirality.

OmicsDI is part of the ELIXIR infrastructure

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Dataset Information

Influence of core size on self-assembled molecular networks composed of C3h-symmetric building blocks through hydrogen bonding interactions: structural features and chirality.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Influence of core size on self-assembled molecular networks composed of C_3h-symmetric building blocks through hydrogen bonding interactions: structural features and chirality.