Aryl sulfonate anion stabilized aromatic triangular cation [Pd₃]⁺: syntheses, structures and properties.

ABSTRACT: A series of sulfonate anions paired aromatic triangular palladium clusters 3-7, abbreviated as [Pd₃]⁺[ArSO₃]^-, were synthesized using a simple "one pot" method, and gave excellent isolated yields (90-95%). Their structures and properties have been fully characterized and further investigated by fluorescence, single crystal X-ray Diffraction (XRD) and X-ray Photoelectron Spectroscopy (XPS). In varying organic solvents, they presented apparently stronger absorption and emission in MeOH, driven by the combined interactions of hydrogen bonds and polarity. The crystallographic data demonstrated that the methyl orange ion stabilized complex 7 possessed a D_3h symmetric metallic core which was still coplanar and almost equilateral, join

SUBMITTER: Wang M 

PROVIDER: S-EPMC10563175 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature