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Syntheses, Crystal Structures, and Catalytic Properties of Three Cu(II) and Cobalt(II) Coordination Compounds Based on an Ether-Bridged Tetracarboxylic Acid.

ABSTRACT: Three new products, [Cu2(μ3-dppa)(2,2'-bipy)2(H2O)]n·2nH2O (1), [Co4(μ4-dppa)2(phen)4(H2O)4]·2H2O (2), and [Co2(μ6-dppa)(μ-4,4'-bipy)(H2O)2]n·3nH2O (3) were synthesized using a hydrothermal method from Cu(II) and Co(II) metal(II) chlorides, 3-(3,4-dicarboxyphenoxy)phthalic acid (H4dppa), and different auxiliary ligands, namely 2,2'-bipyridine (2,2'-bipy),1,10-phenanthroline (phen), and 4,4'-bipyridine (4,4'-bipy). Products 1-3 were characterized by elemental analysis, FTIR, TGA, PXRD, SEM, and single-crystal X-ray crystallography. The structure of 1 features a 1D chain of the 2C1 topological type. Compound 2 shows a discrete tetrameric complex. Product 3 demonstrates a 3D metal-organic framework (MOF) with the new topology. Their structure and topology, thermal stability, and catalytic activity were studied. In particular, excellent catalytic activity was demonstrated for copper(II)-polymer 1 in the cyanosilylation reaction at 35 °C.

SUBMITTER: Kang X 

PROVIDER: S-EPMC10574591 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature

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Syntheses, Crystal Structures, and Catalytic Properties of Three Cu(II) and Cobalt(II) Coordination Compounds Based on an Ether-Bridged Tetracarboxylic Acid.

Kang Xiuqi X   Wang Hongyu H   Mei Zhenzhong Z   Fan Xiaoxiang X   Gu Jinzhong J  

Molecules (Basel, Switzerland) 20231002 19

Three new products, [Cu<sub>2</sub>(<i>μ</i><sub>3</sub><i>-</i>dppa)(2,2'-bipy)<sub>2</sub>(H<sub>2</sub>O)]<i><sub>n</sub></i>·2<i>n</i>H<sub>2</sub>O (<b>1</b>), [Co<sub>4</sub>(<i>μ</i><sub>4</sub><i>-</i>dppa)<sub>2</sub>(phen)<sub>4</sub>(H<sub>2</sub>O)<sub>4</sub>]·2H<sub>2</sub>O (<b>2</b>), and [Co<sub>2</sub>(<i>μ</i><sub>6</sub><i>-</i>dppa)(<i>μ-</i>4,4'-bipy)(H<sub>2</sub>O)<sub>2</sub>]<i><sub>n</sub></i>·3<i>n</i>H<sub>2</sub>O (<b>3</b>) were synthesized using a hydrothermal met  ...[more]

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