Probing the Nano-Assembly Leading to Periodic Gratings in Poly(p-dioxanone).

ABSTRACT: This study used scanning electron microscopy via 3D dissection coupled with synchrotron radiation with microfocal beams of both small-angle X-ray scattering and wide-angle X-ray diffraction to analyze the periodic crystal aggregates of unusual poly(p-dioxanone) (PPDO) dendritic cactus-arm-like ring bands upon crystallization with a diluent poly(vinyl alcohol) (PVA) that is capable of hydrogen bonding interactions with PPDO. Three-dimensional microscopy interior dissection clearly expounds that the banded periodic architectures are packed by alternately normal-oriented flat-on crystals underneath the valley, periodically interfaced/branched with horizontal-oriented edge-on fibrils underneath the ridge. The oblique angles between the valley's flat-on crystals with the branches are ca. 25-45°

SUBMITTER: Hao MH 

PROVIDER: S-EPMC10574605 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature