Controlling the selectivity of the hydrogenolysis of polyamides catalysed by ceria-supported metal nanoparticles.

ABSTRACT: Catalytic hydrogenolysis is a promising approach to transform waste plastic into valuable chemicals. However, the transformation of N-containing polymers, such as polyamides (i.e. nylon), remains under-investigated, particularly by heterogeneous catalysis. Here, we demonstrate the hydrogenolysis of various polyamides catalysed by platinum-group metal nanoparticles supported on CeO₂. Ru/CeO₂ and Pt/CeO₂ are both highly active but display different selectivity; Ru/CeO₂ is selective for the conversion of all polyamides into water, ammonia, and methane, whereas Pt/CeO₂ yields hydrocarbons retaining the carbon backbone of the parent polyamide. Density functional theory computations illustrate that Pt nanoparticles require higher activation

SUBMITTER: Wu X 

PROVIDER: S-EPMC10579319 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature