Selective catalytic synthesis of new terpenic chlorides using NaDCC as an eco-friendly and highly stable FAC agent.

ABSTRACT: A simple, mild and efficient scope pathway for a selective catalytic chlorination of terpenic olefins is investigated in the presence of a highly efficient chlorination agent and a readily available Lewis acid catalyst. The sodium dichloroisocyanurate (NaDCC) used in the present work as an easy handling, sustainable and cost-effective chlorine donor due to its high free available chlorine (FAC), exhibits a high efficiency for selective catalytic chlorination. Herein, we report for the first-time the FeCl₂/NaDCC combination system for the selective catalytic chlorination towards new functionalized terpenic olefins. In order to examine the general features of this catalytic reaction, the effects of pH, solvent, dilution, chlorination agent nature, stoichiometry and reaction kineti

SUBMITTER: Labyad SA 

PROVIDER: S-EPMC10582686 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature