Recovery of 2,3-Butanediol from Fermentation Broth by Zeolitic Imidazolate Frameworks.

ABSTRACT: The efficient separation of the 2,3-butanediol (2,3-BDO) intermediate from fermentation broth is an important issue in the production of biofuels from biomass-derived intermediates. Two zeolitic imidazolate frameworks ZIF-8 and ZIF-71 were investigated for the adsorption of 2,3-butanediol (2,3-BDO) from fermentation broth via liquid breakthrough adsorption measurements. While both ZIF materials initially show high separation performance, ZIF-71 retains robust separation performance even after aging in ethanol for two years, whereas the capacity of ZIF-8 decreases significantly. The robustness and stability of ZIF-71 are further confirmed with cyclic fixed bed adsorption measurements. The uptake of 2,3-BDO on ZIF-71 reaches >100 g/kg with negligible uptakes of sugars, organic acids, and oth

SUBMITTER: Chiang Y 

PROVIDER: S-EPMC10588442 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature