On-surface synthesis of nitrogen-doped nanographene with an [18]annulene pore on Ag(111).

ABSTRACT: On-surface synthesis is of importance to fabricate low dimensional carbon-based nanomaterials with atomic precision. Here, we synthesize nitrogen-doped nanographene with an [18]annulene pore and its dimer through sequential reactions of debromination, aryl-aryl coupling, cyclodehydrogenation and C-N coupling on Ag(111) from 3,12-dibromo-7,8-diaza[5]helicene. The inner structures of the products were characterized with scanning tunneling microscopy with a CO terminated tip at low temperature. Furthermore, the first four unoccupied electronic states of the nanographene were investigated with a combination of scanning tunneling spectroscopy and theoretical calculations. Except for the LUMO + 2 state observed at +1.3 V, the electronic states at 500 mV, 750 mV and 1.9 V were attributed to the s

SUBMITTER: Sun K 

PROVIDER: S-EPMC10589310 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature