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Processing on crystal growth, structure, thermal property, and nuclear magnetic resonance of organic-inorganic hybrid perovskite type [NH3(CH2)6NH3]ZnCl4 crystal.


ABSTRACT: Organic-inorganic hybrid compounds have recently gained significant attention in recent years due to their diverse applications. Herein, [NH3(CH2)6NH3]ZnCl4 crystals were grown, and their triclinic structure, phase transition temperature (TC = 408 K), and high thermal stability (Td = 584 K) was determined using X-ray diffraction (XRD), differential scanning calorimetry, and thermogravimetry measurements. By analyzing the chemical in response to temperature changes, we observed that the coordination geometry around 1H and 13C were highly symmetric below TC, whereas their symmetry was lowered above TC. The change of N-H⋯Cl hydrogen bond from XRD

SUBMITTER: Lim AR 

PROVIDER: S-EPMC10601597 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature