Selective Deionization of Thin-Layer Samples Using Tandem Carbon Nanotubes-Polymeric Membranes.

ABSTRACT: Herein, we investigate the selective deionization (i.e., the removal of ions) in thin-layer samples (<100 μm in thickness) using carbon nanotubes (CNTs) covered with an ionophore-based ion-selective membrane (ISM), resulting in a CNT-ISM tandem actuator. The concept of selective deionization is based on a recent discovery by our group ( Anal. Chem. 2022, 94, 21, 7455-7459), where the activation of the CNT-ISM architecture is conceived on a mild potential step that charges the CNTs to ultimately generate the depletion of ions in a thin-layer sample. The role of the ISM is to selectively facilitate the transport of only one ion species to the CNT lattice. To estimate the deionization efficiency of such a process, a potentiometric sensor is placed less than 100 μm away from the CNT-ISM

SUBMITTER: Wiorek A 

PROVIDER: S-EPMC10603610 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature