Strong Coupling of Coherent Phonons to Excitons in Semiconducting Monolayer MoTe₂.

ABSTRACT: The coupling of the electron system to lattice vibrations and their time-dependent control and detection provide unique insight into the nonequilibrium physics of semiconductors. Here, we investigate the ultrafast transient response of semiconducting monolayer 2H-MoTe₂ encapsulated with hBN using broadband optical pump-probe microscopy. The sub-40 fs pump pulse triggers extremely intense and long-lived coherent oscillations in the spectral region of the A' and B' exciton resonances, up to ∼20% of the maximum transient signal, due to the displacive excitation of the out-of-plane A_1g phonon. Ab initio calculations reveal a dramatic rearrangement of the optical absorption of monolayer MoTe₂ induced by an out-of-plane stretching and compres

SUBMITTER: Sayers CJ 

PROVIDER: S-EPMC10603802 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature