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Enhanced Sorption Performance of Natural Zeolites Modified with pH-Fractionated Humic Acids for the Removal of Methylene Blue from Water.


ABSTRACT: This work explores the effect of humic acids (HA) fractionation on the sorption ability of a natural zeolite (NYT)-HA adduct. HA were extracted from compost, fractionated via the pH fractionation method, and characterized via UV-Vis spectroscopy and gel permeation chromatography. The HA samples were immobilized onto NYT via thermal treatment. The resulting adducts (NYT-HA) were tested for their ability to remove methylene blue (MB) from an aqueous solution. It was found that the sorption performance of NYT-HA strongly depends on the chemical characteristics of humic acids. Sorption capacity increased with the molecular weight and hydrophobicity degree of the HA fractions. Hydrophobic and π-π interactions are likely the primary mechanisms by which MB interacts with HA. The sorption kinetic data conform to the pseudo-second-order model. The Freundlich isotherm model adequately described the sorption equilibrium and revealed that the uptake of MB onto NYT-HA is endothermic in nature.

SUBMITTER: Salvestrini S 

PROVIDER: S-EPMC10609103 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature

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Enhanced Sorption Performance of Natural Zeolites Modified with pH-Fractionated Humic Acids for the Removal of Methylene Blue from Water.

Salvestrini Stefano S   Debord Jean J   Bollinger Jean-Claude JC  

Molecules (Basel, Switzerland) 20231014 20


This work explores the effect of humic acids (HA) fractionation on the sorption ability of a natural zeolite (NYT)-HA adduct. HA were extracted from compost, fractionated via the pH fractionation method, and characterized via UV-Vis spectroscopy and gel permeation chromatography. The HA samples were immobilized onto NYT via thermal treatment. The resulting adducts (NYT-HA) were tested for their ability to remove methylene blue (MB) from an aqueous solution. It was found that the sorption perform  ...[more]

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