Catalytic ozonation mechanism over M₁-N₃C₁ active sites.

ABSTRACT: The structure-activity relationship in catalytic ozonation remains unclear, hindering the understanding of activity origins. Here, we report activity trends in catalytic ozonation using a series of single-atom catalysts with well-defined M₁-N₃C₁ (M: manganese, ferrum, cobalt, and nickel) active sites. The M₁-N₃C₁ units induce locally polarized M - C bonds to capture ozone molecules onto M atoms and serve as electron shuttles for catalytic ozonation, exhibiting excellent catalytic activities (at least 527 times higher than commercial manganese dioxide). The combined in situ characterization and theoretical calculations reveal single metal atom-dependent catalytic activity, with surface atomic oxygen reactivity identified as a

SUBMITTER: Ma D 

PROVIDER: S-EPMC10622452 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature