Poly[bis-(O-ethyl-hydroxy-laminium) [di-μ-chlorido-di-chlorido-cadmate(II)]].

ABSTRACT: The title compound, {(CH₃CH₂ONH₃)₂[CdCl₄]}_n, consists of bilayers of organic CH₃CH₂ONH₃ ⁺ cations and infinite [CdCl₄]_n ^2n- inorganic layers. It can be described as an organic-inorganic hybrid layered perovskite. In the crystal structure, the Cd^II cation is situated at an inversion center and is coordinated by six chloride ions, forming a slightly distorted octa-hedral coordination polyhedron. By corner-sharing of the [CdCl₆] octa-hedra, infinite [CdCl₄]_n ^2n- inorganic layers are formed, extending parallel to (100). The inorganic layers alternate with bilayers

SUBMITTER: Tong YQ 

PROVIDER: S-EPMC10626843 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature