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Poly[[(μ₃-adamantane-1,3-di-acetato)[μ-N-(pyridin-3-yl)isonicotinamide]-nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology.

ABSTRACT: The title compound, {[Ni(C₁₄H₁₈O₄)(C₁₁H₉N₃O)]·H₂O}_n, contains octa-hedrally coordinated Ni^II ions ligated by 1,3-adamantanedi-acetato (ada) ligands and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands, to form coordination polymer layers with a triangular (3,6) grid topology based on [Ni₂(OCO)₂] dimeric units. The diperiodic layer motifs stack in an ABAB pattern mediated by C-H⋯O supra-molecular inter-actions between ada ligands and water mol-ecules of crystallization to form the full triperiodic crystal structure of the title compound.

SUBMITTER: Travis JZ

PROVIDER: S-EPMC10626845 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature

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Poly[[(μ₃-adamantane-1,3-di-acetato)[μ-N-(pyridin-3-yl)isonicotinamide]-nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology.

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Dataset Information

Poly[[(μ3-adamantane-1,3-di-acetato)[μ-N-(pyridin-3-yl)isonicotinamide]-nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Poly[[(μ₃-adamantane-1,3-di-acetato)[μ-N-(pyridin-3-yl)isonicotinamide]-nickel(II)] monohydrate], a layered coordination polymer with triangular (3,6) topology.