[(1,2,5,6-η)-Cyclo-octa-1,5-diene](1-ethyl-4-isopropyl-1,2,4-triazol-5-yl-idene)(tri-phenylphos-phane)iridium(I) tetra-fluorido-borate di-chloro-methane sesquisolvate.

ABSTRACT: The synthesis and crystal structure of a new triazole-based N-heterocyclic carbene iridium(I) cationic complex with a tetra-fluorido-borate counter-anion and solvating di-chloro-methane, [Ir(C₈H₁₂)(C₇H₁₃N₃)(C₁₈H₁₅P)]BF₄·1.5CH₂Cl₂, is reported. The Ir^I center of the cationic complex has a distorted square-planar conformation, formed by a bidentate cyclo-octa-1,5-diene (COD) ligand, an N-heterocyclic carbene, and a triphenylphosphane ligand. There are weak hydrogen-bonding inter-actions between C-H groupings of the iridium complex and F atoms of the [BF₄]^- counter-ions. The atoms of the COD ligand are disordered over two sets of sites in a 0.65:0.35 r

SUBMITTER: Maynard A 

PROVIDER: S-EPMC10626851 | biostudies-literature | 2023 Oct

REPOSITORIES: biostudies-literature