Synthesis, crystal structure and Hirshfeld surface analysis of di-aqua-bis-(o-phenyl-enedi-amine-κ²N,N')nickel(II) naphthalene-1,5-di-sulfonate.

ABSTRACT: The reaction of o-phenyl-enedi-amine (OPD), sodium naphthalene1,5-di-sulfonate (Na₂NDS) and nickel sulfate in an ethanol-water mixture yielded the title compound, [Ni(OPD)₂(H₂O)₂]·NDS or [Ni(C₆H₈N₂)₂(H₂O)₂](C₁₀H₆O₆S₂). This salt consists of a complex [Ni(OPD)₂(H₂O)₂]²⁺ cation with two bidentate OPD ligands and trans aqua ligands, and a non-coordinating NDS^2- anion, which is the double-deprotonated form of H₂NDS. The Ni^II atom is situated at a center of inversion and exhibits a slightly tetra-gonally distorted {O₂N₄} octa-hedral

SUBMITTER: Suyunov JR 

PROVIDER: S-EPMC10626944 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature