Synthesis, crystal structure and Hirshfeld surface analysis of di-acetato-bis-[4-(2-amino-eth-yl)morpholine]cadmium tetra-hydrate.

ABSTRACT: The title coordination compound, [Cd(C₂H₃O₂)₂(C₆H₁₄N₂O)₂]·4H₂O, was synthesized by mixing 2 moles of 4-(2-amino-eth-yl)morpholine and 1 mole of cadmium acetate in double-distilled water. The Cd atom is octa-hedrally coord-inated by two N,N'-bidentate ligands [4-(2-amino-eth-yl)morpholine] and two trans-located acetate mol-ecules. The Cd atom is located on a center of inversion, whereas the 4-(2-amino-eth-yl)morpholine and four water mol-ecules are adjacent to the acetate mol-ecules. The chair conformation of the morpholine mol-ecules is confirmed. In the crystal, adjacent metal complexes and uncoord-inated water mol-ecules are linked via N-H⋯O and O-H⋯O hydrogen-bo

SUBMITTER: Chidambaranathan B 

PROVIDER: S-EPMC10626961 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature