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Crystal structure and Hirshfeld surface analysis of poly[[tetra-aqua-(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodeca-aza-tetra-cyclo-[8.8.4.1^3,17.1^8,12]tetra-cosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetra-hydrate].

ABSTRACT: The title compound, [FeLi₂(C₁₂H₁₂N₁₂O₆)(H₂O)₄]·4H₂O, consists of iron complex anions, lithium cations and water mol-ecules. The complex anion shows a clathrochelate topology. The coordination geometry of the Fe^IV centre is inter-mediate between a trigonal prism and a trigonal anti-prism. In the crystal, the complex anions are connected through two Li cations into dimers, which are connected by Li-O bonds, forming infinite chains along the b-axis direction.

SUBMITTER: Plutenko MO

PROVIDER: S-EPMC10626965 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature

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Crystal structure and Hirshfeld surface analysis of poly[[tetra-aqua-(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodeca-aza-tetra-cyclo-[8.8.4.1^3,17.1^8,12]tetra-cosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetra-hydrate].

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Crystal structure and Hirshfeld surface analysis of poly[[tetra-aqua-(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodeca-aza-tetra-cyclo-[8.8.4.13,17.18,12]tetra-cosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetra-hydrate].

OmicsDI is part of the ELIXIR infrastructure

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Crystal structure and Hirshfeld surface analysis of poly[[tetra-aqua-(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodeca-aza-tetra-cyclo-[8.8.4.1^3,17.1^8,12]tetra-cosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetra-hydrate].