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Synthesis, crystal structure and Hirshfeld analysis of trans-bis-{(2E)-N-phenyl-2-[(2E)-3-phenyl-2-propen-1-yl-idene]hydrazinecarbo-thio-amidato-κ²N¹,S}palladium(II).

ABSTRACT: The reaction of (2E)-N-phenyl-2-[(2E)-3-phenyl-2-propen-1-yl-idene]hydra-zine-carbo-thio-amide (common name: cinnamaldehyde-4-phenyl-thio-semi-carbazone) deprotonated with NaOH in ethanol with an ethano-lic suspension of Pd^II chloride in a 2:1 molar ratio yielded the title compound, [Pd(C₁₆H₁₄N₃S)₂]. The anionic ligands act as metal chelators, κ² N ¹ S-donors, forming five-membered rings with a trans-configuration. The Pd^II ion is fourfold coordinated in a slightly distorted square-planar geometry. For each ligand, one H⋯S and one H⋯N intra-molecular inter-actions are observed, with S(5) and S(6) graph-set motifs. Concerning the H⋯S inter-actions,

SUBMITTER: de Melo APL

PROVIDER: S-EPMC10626968 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature

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Synthesis, crystal structure and Hirshfeld analysis of trans-bis-{(2E)-N-phenyl-2-[(2E)-3-phenyl-2-propen-1-yl-idene]hydrazinecarbo-thio-amidato-κ²N¹,S}palladium(II).

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Dataset Information

Synthesis, crystal structure and Hirshfeld analysis of trans-bis-{(2E)-N-phenyl-2-[(2E)-3-phenyl-2-propen-1-yl-idene]hydrazinecarbo-thio-amidato-κ2N1,S}palladium(II).

OmicsDI is part of the ELIXIR infrastructure

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Synthesis, crystal structure and Hirshfeld analysis of trans-bis-{(2E)-N-phenyl-2-[(2E)-3-phenyl-2-propen-1-yl-idene]hydrazinecarbo-thio-amidato-κ²N¹,S}palladium(II).