Copper-promoted S-arylation reactions with triarylbismuths for the synthesis of diaryl sulfides.

ABSTRACT: A simple approach for copper-promoted S-arylation reactions utilizing triarylbismuths or triarylantimonys as arylating reagents has been described. These reactions can be performed under mild conditions and exhibit remarkable functional group tolerance and chemoselectivity. The corresponding 2-arylthiopyridine 1-oxide derivatives and arylthioanilines/phenols have been successfully synthesized, achieving good to excellent yields across over 49 examples.

SUBMITTER: Nie M 

PROVIDER: S-EPMC10636603 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature