3D printable soft and solvent-free thermoplastic elastomer containing dangling bottlebrush chains.

ABSTRACT: Polymer networks containing bottlebrush chains are emerging materials with exceptionally soft and highly tunable mechanical properties. However, such materials have not been extensively implemented in functional processing techniques such as three-dimensional (3D) printing. Here, we introduce a new design of soft and solvent-free polydimethylsiloxane (PDMS)-based thermoplastic elastomer which contains dangling and space-filling bottlebrush chains, featuring a yield stress and a rapid recovery after stress removal; both required for high spatial fidelity 3D printing. The developed material is composed of two copolymers; the main building block is a diblock copolymer with linear polystyrene (PS) block and bottlebrush PDMS block (PS-b-bbPDMS) while the second component is PS-b-P

SUBMITTER: Asadi V 

PROVIDER: S-EPMC10642180 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature