Hydrazine-Assisted Acidic Water Splitting Driven by Iridium Single Atoms.

ABSTRACT: Water splitting, an efficient technology to produce purified hydrogen, normally requires high cell voltage (>1.5 V), which restricts the application of single atoms electrocatalyst in water oxidation due to the inferior stability, especially in acidic environment. Substitution of anodic oxygen evolution reaction (OER) with hydrazine oxidation reaction (HzOR) effectually reduces the overall voltage. In this work, the utilization of iridium single atom (Ir-SA/NC) as robust hydrogen evolution reaction (HER) and HzOR electrocatalyst in 0.5 m H₂ SO₄ electrolyte is reported. Mass activity of Ir-SA/NC is as high as 37.02 A mg_Ir ^-1 at overpotential of 50 mV in HER catalysis, boosted by 127-time than Pt/C. Besides, Ir-SA/NC requires only 0.39 V versus RHE

SUBMITTER: Luo F 

PROVIDER: S-EPMC10646228 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature