A Cu^ICo^II cryptate for the visible light-driven reduction of CO₂.

ABSTRACT: Among the rare bimetallic complexes known for the reduction of CO₂, Co^IICo^II and Zn^IICo^II hexamine cryptates are described as efficient photocatalysts. In close relation to the active sites of natural, CO₂-reducing enzymes, we recently reported the asymmetric cryptand {N^SN^N}_m ({N^SN^N}_m = N[(CH₂)₂SCH₂(m-C₆H₄)CH₂NH(CH₂)₂]₃N) comprising distinct sulphur- and nitrogen-rich binding sites and the corresponding Cu^IM^II (M^II = Co^II, Ni^II, Cu^II) complexes. To gain insight into the effect of metals in d

SUBMITTER: Jokel J 

PROVIDER: S-EPMC10646873 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature