Isoreticular Chemistry and Applications of Supramolecularly Assembled Copper-Adenine Porous Materials.

ABSTRACT: The useful concepts of reticular chemistry, rigid and predictable metal nodes together with strong and manageable covalent interactions between metal centers and organic linkers, have made the so-called metal-organic frameworks (MOFs) a flourishing area of enormous applicability. In this work, the extension of similar strategies to supramolecularly assembled metal-organic materials has allowed us to obtain a family of isoreticular compounds of the general formula [Cu₇(μ-adeninato-κN3:κN9)₆(μ₃-OH)₆(μ-OH₂)₆](OOC-R-COO)·nH₂O (R: ethylene-, acetylene-, naphthalene-, or biphenyl-group) in which the rigid copper-adeninato entities and the organic dicarboxylate anions are held together not by covalen

SUBMITTER: Mena-Gutierrez S 

PROVIDER: S-EPMC10647167 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature