A Pair of Multifunctional Cu(II)-Dy(III) Enantiomers with Zero-Field Single-Molecule Magnet Behaviors, Proton Conduction Properties and Magneto-Optical Faraday Effects.

ABSTRACT: Multifunctional materials with a coexistence of proton conduction properties, single-molecule magnet (SMM) behaviors and magneto-optical Faraday effects have rarely been reported. Herein, a new pair of Cu(II)-Dy(III) enantiomers, [DyCu₂(RR/SS-H₂L)₂(H₂O)₄(NO₃)₂]·(NO₃)·(H₂O) (R-1 and S-1) (H₄L = [RR/SS] -N,N'-bis [3-hydroxysalicylidene] -1,2-cyclohexanediamine), has been designed and prepared using homochiral Schiff-base ligands. R-1 and S-1 contain linear Cu(II)-Dy(III)-Cu(II) trinuclear units and possess 1D stacking channels within their supramolecular networks. R-

SUBMITTER: Zhu SD 

PROVIDER: S-EPMC10673516 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature