Extent of carbon nitride photocharging controls energetics of hydrogen transfer in photochemical cascade processes.

ABSTRACT: Graphitic carbon nitride is widely studied in organic photoredox catalysis. Reductive quenching of carbon nitride excited state is postulated in many photocatalytic transformations. However, the reactivity of this species in the turn over step is less explored. In this work, we investigate electron and proton transfer from carbon nitride that is photocharged to a various extent, while the negative charge is compensated either by protons or ammonium cations. Strong stabilization of electrons by ammonium cations makes proton-coupled electron transfer uphill, and affords air-stable persistent carbon nitride radicals. In carbon nitrides, which are photocharged to a smaller extent, protons do not stabilize electrons, which results in spontaneous charge transfer to oxidants. Facile proton-couple

SUBMITTER: Savateev O 

PROVIDER: S-EPMC10674013 | biostudies-literature | 2023 Nov

REPOSITORIES: biostudies-literature